Yes, and you have plenty of choice. After arriving at Franz Josef Strauss Intl. Airport (MUC), simply walk to the rental car center at the Rental Car Center, Terminalstraße Mitte - Munich Airport Center - Level 03. Here you can book from trusted companies like Hertz/Dollar/Thrifty, Avis/Budget and Sixt/Flizzr. If you’re after more options, check out the deals from Alamo/Enterprise/National and Europcar/Rent-A-Car/Global.